Multi-frequency EPR can play under different frequency of EPR spectroscopy analysis.At present, brooke's EPR products series of microwave frequency including two orders of magnitude:
L - and S - Band: 1 GHz and 3.5 GHz
X - Band: the most commonly used frequency of 9.8 GHz
Q - Band: 34 GHz
W - Band: 94 GHz
Mm - wave: 263 GHz
The high frequency of EPR advantages obviously, but low frequency EPR is bulk sample, especially the best choice for living research (ELEXSYS E540).
Multi-frequency EPR spectrum can be fitting more efficiently.Sports effect, moreover, can be in a wide range of time for study.
Multiple frequency the CW - EPR
Most of the CW EPR system on x-band as working frequency.Therefore, entering the multifrequency the CW - the first step of EPR, is to use another operating frequency.In terms of conventional the CW - EPR spectrum, 34 GHz Q band is the best choice, because:
Q band can provide Zeemann energy is three times higher
Can hold the sample volume is still considerable, diameter up to 3 mm
Available with optional window or Q band probe function of ENDOR
The following table lists the most common form of EPR spectrum, their frequency range, and corresponds to the free radical species g = 2 of the magnetic field value (details refer toWhat is the EPR?The CW EPR theory).All these frequencies are usually available in matching brooke magnet system under the premise of providing series.
L | s. | X | Q | W. | |
V/GHz. | 0.8-1.2 | 3.4-3.8 | 9-10 | 34 | 94 |
G = 2 / kG | 0.35 | 1.3 | 3.4 | 12.2 | 33.5 |
Brooke's multifrequency EPR is not limited to the CW - EPR.Brooke's EPR products in continuous wave and pulse mode can be truly multi-frequency and more resonance EPR, ENDOR and ELDOR.For example, because of the concept of intermediate frequency (IF) x-band E580 system can easily upgrade to Q band (SuperQ - FT).